Visible light promoted carbodifluoroalkylation of allylic alcohols via concomitant 1,2-aryl migration.
نویسندگان
چکیده
A novel visible light promoted carbodifluoroalkylation of allylic alcohols is disclosed. A series of difluoro 1,5-dicarbonyl compounds were obtained through a tandem radical addition and 1,2-aryl migration process. Mechanistic analysis indicated that the 1,2-aryl rearrangement proceeded via a radical intermediate.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 33 شماره
صفحات -
تاریخ انتشار 2015